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Chem-News November/December 1990

DATE:        November/December, 1990
TO:          Those Interested in Pesticide Information
FROM:        William G. Smith, Senior Extension Associate
INDEX
                                                                          Page
Azinphos-Methyl; Certain Agricultural Uses Deleted                          1
NYS Dept. of Ag. & Mkts. Food Lab. October/November Report                  2
FDA Pesticide Residue Monitoring Plans Noted                                3
EPA Notes Voluntary Cancellation of 4 Amitrole Products                     3
White House Minor Use Task Force Makes Recommendations                      3
Pesticide Export Provision Dropped From Farm Bill                           4
EPA To Encourage Non-Chemical Pest Controls, Campt Says                     5
Revised Applicator Certification Training Proposal Issued                   5
USDA Amends Regulations To Import Certain Fruits From Chile                 6
Pesticide Poisonings To Be Reported                                         6
Update on Cornell's Pesticide Needs and Alternatives Survey                 7
USEPA Well Water Survey                                                     7
News Briefs                                                                 9
* * * * * * * * * * 
Azinphos-Methyl; Deletion of Certain Uses and Directions for Use for 
Agricultural Crops
SUMMARY:  This notice announces that Mobay Chemical Corporation, one of the 
four producers of the technical active ingredient azinphos-methyl in the 
United States has requested to amend its registrations of Guthion Technical 
(EPA reg. no. 3125-108), Guthion 25% Wettable Powder Insecticide for 
Repackaging of an Insecticide (EPA reg. no. 3125-153), Guthion 22 Concentrate 
(EPA reg. no. 3125-223), Guthion Garden Spray Insecticide for Repackaging of 
an Insecticide Only (EPA reg. no. 3125-225), Guthion 50% Wettable Powder (EPA 
reg. no. 3125-193), Guthion 50% Wettable Powder in Water Soluble Packets (EPA 
reg. no. 3125-301), Guthion 35% Wettable Powder (EPA reg. no. 3125-378), 
Guthion 35% Wettable Powder in Water Soluble Packets (EPA reg. no. 3125-179), 
Guthion 2L (EPA reg. no. 3125-102), and Guthion 2S (EPA reg. no. 3125-123) by 
deleting all uses and directions for use on the following 22 agricultural 
crops: apricots, barley, beans, blackberries, boysenberries, broccoli, 
brussels sprouts, cabbage, cauliflower, celery, clover, grass mixture, 
loganberries, oats, pasture grasses, peas, raspberries, rye, soybeans, 
spinach, tobacco, and wheat. EPA is at this time soliciting comments on the 
proposed amendments.
SUPPLEMENTARY INFORMATION:  Azinphos-methyl is the commonly accepted name for 
O,O-dimethyl-S-[(4-oxo-1,2,3-benzotriazin-3 (4H)-yl)methyl]phosphor-dithioate.  
It is a broad spectrum organophosphate insecticide that was initially 
registered as a pesticide under FIFRA in 1957 by Mobay Chemical Corporation.  
Azinphos-methyl is primarily used in the formulation of insecticide products 
for use on terrestrial food crops and terrestrial non-food crops.  Azinphos-
methyl is marketed by Mobay Chemical Corporation under the trade name Guthion.  
Mobay, one of the four registrants of technical grade azinphos-methyl, has 
requested to amend their registrations for Guthion products by deleting all 
uses and directions for use on the 22 crops listed in this notice.  EPA 
intends to approve this request.  Since there will no longer be Guthion 
manufacturing use products available from which to formulate registered end-
use azinphos-methyl products on the 22 crops, the other three registrants, 
Aceto Chemical Company, Makhteshim-Aagan (America) lnc., and Gowan Company, 
are being notified by certified mail that they are being given the opportunity 
to generate data in support of the reregistration of azinphos-methyl for the 
22 crops listed in this notice.  End-use registrants of azinphos-methyl are 
being notified by certified mail that their generic data exemption is not 
valid for these uses.  In the event that Aceto Chemical Company, Makhteshim-
Agan (America) Inc., or Gowan Company, do not generate the data necessary to 
re-register the use of azinphos-methyl for the 22 crops listed in this notice, 
end-use registrants will be given opportunity to generate data in support of 
these uses.  EPA is now soliciting comments on the proposed amendments.  
Interested persons are invited to submit written comments to the address given 
above.
     -- Federal Register, 10/31/90
New York State Department of Agriculture and Markets Food Laboratory Monthly 
Report for October/November, 1990
     Food Laboratory personnel analyzed the following number of food samples 
during October, 1990:
         Number of
         Samples        Agency
         __________     _______________________________
              1         New York State Health Department
                        Department of Agriculture and Markets
            762         Food Inspection Services
              4         Kosher Inspection
          1,559         Milk Control
          _____
Total     2,326
     Pesticides were not found in 79 percent of the samples.  Approximately 
one percent contained residues in excess of tolerances. Domestic tomatoes 
contained 0.19 ppm DDE and TDE.
     During the month of November, 73 samples of milk and various food 
products were analyzed.  Residues were not detected in any of the 20 fluid 
milk samples.  Detectable residues also were not found in 66 percent of the 
fruit and vegetable samples analyzed.  Official tolerances were not exceeded 
in the remaining 18 samples.
     -- NYS Agriculture & Markets Food Report
FDA Pesticide Residue Monitoring Plans Noted
     FDA has outlined plans for analyzing about 20,000 samples of hundreds of 
domestic and imported food for residues of 600-700 pesticide active 
ingredients.  Monitoring will cover commodities from over 100 exporting 
countries.  Commodities, pesticides, countries and states covered will vary 
from year to year.  Of the 600-700 active ingredients, FDA has selected 225 
parent pesticides and put them in three priority groups.  The 225 will be 
covered over the next several years, according to "Pesticide Residue 
Monitoring:  Information and Planning Materials for FDA's Monitoring Program," 
Center for Food Safety and Applied Nutrition.
     FDA cannot ensure that every food shipment containing a violative 
pesticide residue is intercepted; rather, the agency conducts its pesticide 
program to uncover major pesticide residue problems, which, when identified, 
can be remedied to prevent future violations," according to the materials.
     -- Pesticide & Toxic Chemical News, Oct. 17, 1990
EPA Notes Voluntary Cancellation of 4 Amitrole Products
     In the Oct. 15 Federal Register, EPA published a notice of receipt of a 
request from Rhone-Poulenc for voluntary cancellation of four amitrole 
registrations, effective Oct. 25, 1990.  The products can be sold, distributed 
or released for shipment until Sept. 1, 1991.  End-users may use the products 
until supplies are exhausted, the notice said.
     The four:  Weedazol, Amizine, Liquid Amizine, and Amitrol T (Lawn and 
Garden).
     -- Pesticide & Toxic Chemical News, Oct. 17, 1990
White House Minor Use Task Force Makes Recommendations
     A White House Minor Use Task Force has filed a five-page final report 
which makes recommendations for extensive changes, including:
     -- Define minor use and minor crop in a tiered way so that "if the use is 
minor, the degree of 'minorness' would be established by clearly defined 
dietary exposure criteria.  Registration data would be commensurate with the 
'minorness' of each particular crop/pesticide combination.  This approach 
would facilitate minor crop registration by relating data requirements to the 
degree of dietary exposure."
     -- Change the crop grouping scheme, following study, possibly by using 
different representative crops or subgroups.
     -- "EPA should permit greater bridging of data between two or more crops 
with similar residue potential.
     -- "Minor crop pesticide registrations would be facilitated by permitting 
geographically restricted registrations for all minor crops based on 
appropriate geographical residue data.  Registrations could be expanded if 
additional residue data become available.  This could hasten the availability 
of minor use registrations in regions of greatest need without delays incurred 
by a geographically limited data base."
     -- Permit the "provisional use of pesticides on minor crops based on 
established Codex Maximum Residue Limits (MRLs) where no actual residues are 
likely to occur."
     -- Exempt registrants from maintenance fees for special local need labels 
on minor crops.
     -- Use conditional registrations and reregistrations more widely than at 
present to address minor use problems.
     -- "EPA should adopt a policy of flexible reregistration data submission 
schedules for minor crop tolerances with deadlines based on the farthermost 
study due date."
     -- Expedite registration of biorational agents.
     -- Legislative changes:  Move toward FIFRA revisions based on recommenda-
tions of a government-industry-user task force, and provide tax incentives for 
registrants which support minor uses and minor use registration projects.
     -- Encourage third party registrations and explore liability waivers.
     -- Pesticide & Toxic Chemical News, Oct. 17, 1990
Pesticide Export Provision Dropped From Farm Bill
     The pesticide export provision was dropped from the farm bill by the 
Senate-House Conference Committee, which also eliminated all pesticide 
container measures, and basically adopted the Senate version of the minor use 
amendment and the Senate version of IR-4 provisions.  The bill has an IPM 
research provision, and a pesticide use record-keeping requirement.
     Provisions of the pesticide use amendment agreed to by the conferees at 
3:45 a.m. Oct. 16 include: covers restricted use pesticides; has the House 
language on medical access; provides for federal and state agency access to 
the records; no worker access, and farmers would be held harmless under other 
federal and state laws.  Still to be worked out by staff at press time is the 
matter of how federal agencies will make records available without release of 
farmers' names and locations.
     -- Pesticide & Toxic Chemical News, Oct. 17, 1990
EPA To Encourage Non-Chemical Pest Controls, Campt Says
     "EPA will increase its support for research on low- or non-chemical 
methods of pest control and encourage the development of biological and other 
low-toxicity products through incentives in the registration process," Douglas 
Campt, Director, OPP, EPA, noted in a speech last week to the California 
Agricultural Production Consultants Association meeting in Costa Mesa. The 
impetus for this increased research is the agency's new emphasis on pollution 
prevention, he said. The OPP Director also noted that EPA is developing a 
"safer pesticides" policy "to expedite the registration of new products that 
can replace some of the riskier pesticides now in use."
     -- Pesticide & Toxic Chemical News, November 7,1990
Revised Applicator Certification Training Proposal Issued
     The EPA's proposed revised application certification and training 
regulations was published in the Federal Register on Nov. 7, with 120 days 
allowed for comment.  The proposal requires the same general standards of 
competency for both commercial and private applicators.
     The "use" definition in the proposal "means performance of the following 
pesticide-related activities requiring certification:  application; mixing; 
loading; transport, storage or handling after manufacturer's seal is broken; 
care and maintenance of application and handling equipment; and disposal of 
pesticides and their containers in accordance with label requirements.  There 
are uses not requiring certification under this part, such as long-distance 
transport, long-term storage, or ultimate disposal."
     The proposal would drop the exemption for doctors of medicine and 
veterinary medicine.
     Applicator recertification would be required at least every five years.
     And, the proposal would impose specific training requirements for non-
certified applicators.
     Under the proposal, there would be four private and 11 commercial 
applicator categories.
     -- Pesticide & Toxic Chemical News, November 7,1990
USDA Amends Regulations To Import Certain Fruits From Chile
     WASHINGTON, Oct. 19-The U.S. Department of Agriculture has amended its 
regulations to allow the importation of stonefruit (apricots, nectarines, 
peaches and plums) from Chile based on pre-clearance inspection, as long as 
certain precautions are taken.  Importation based on fumigation, which was 
previously mandatory, is still an accepted option.
     Precautions include inspection of the fruit in Chile.  Also, all 
shipments must be completely covered with tarpaulins, or be enclosed in 
containers or sealed trucks during movement from the inspection facility to 
the vessel or aircraft.
     Activities to determine the eligibility of these kinds of fruit shipments 
to the United States, are called "pre-clearance" to distinguish them from 
similar inspections, treatments and other procedures performed by APHIS 
inspectors at ports of arrival in the United States.  Inspections conducted in 
Chile are comparable in effectiveness to inspections at the port of entry in 
the United States.
     These pre-clearance inspections are performed under the direction of 
APHIS inspectors in Chile and are carried out either by APHIS inspectors or by 
inspectors of the national plant protection service of Chile in the presence 
of APHIS inspectors.  Fruit pre-cleared in Chile does not normally require 
reinspection at U.S. ports.
     The amended regulations will be published in the Oct. 19 Federal Register 
and will take effect Nov. 19.
     -- USDA, Selected Speeches and News Releases, Oct. 18-25, 1990
Pesticide Poisonings To Be Reported
     Pesticide poisonings have recently been added to the list of reportable 
medical conditions in New York.  Under these regulations, physicians and 
health facilities are required to report, to the New York State Department of 
Health (NYSDOH), any patient with confirmed or suspected pesticide poisoning.  
Clinical laboratories are required to report blood cholinesterase levels and 
levels of pesticides in human tissue which are outside the normal range 
established by the laboratory.
     All reports of confirmed or suspected pesticide poisonings in New York 
will be investigated by staff working with the newly formed pesticide registry 
within the Division of Environmental Epidemiology and Occupational Health at 
the NYSDOH.  The goals of the registry are to (1) determine the occurrence of 
pesticide poisonings in New York, (2) monitor both the acute and chronic 
effects of pesticide exposure, (3) promptly investigate and intervene in any 
situations where the risk of pesticide poisonings is continuing, (4) develop 
and implement interventions to reduce the risks of pesticide poisoning, and 
(5) increase the awareness of pesticide poisonings by members of the medical 
community.
     Medical and laboratory personnel should report all suspected pesticide 
poisonings directly to the NYS PESTICIDE POISONINGS REGISTRY at 1-800-322-
6850.  For further information regarding the NYS pesticide poisonings 
registry, please feel free to contact the Bureau of Occupational Health at 
518-458-6228.
     -- NYS Department of Health
Update on Cornell's Pesticide Needs and Alternatives Survey
     In the September issue of Chem-News, Cornell's Chemicals-Pesticides 
Program announced its National Agricultural Pesticide Impact Assessment 
Program (NAPIAP) funded project to survey New York growers relative to 
pesticide use, needs, and alternatives for production of field corn, small 
grains, alfalfa, cauliflower, snap beans, onions and sweet corn.
     The data generated through this survey will provide NAPIAP with benefits 
information for the Current Benefits Review portion of the Risk/Benefit 
analysis (for a pesticide active ingredient) in the EPA's Special Review 
process.  
     To gather the information, the Chemicals-Pesticides Program has designed 
a one-hour pesticide education course which will offer growers 2.0 hours of 
recertification credit (formerly only one credit).  The course will cover the 
following topics:  The Special Review Process, Pesticide Recording Keeping and 
Pesticide Safety/Label Review as well as filling out the short survey form.
     It is still possible for agents/specialists to schedule a course for 
growers by contacting the Chemicals-Pesticides Program.  To complete the 
survey questionnaire, it would be helpful if growers brought along their most 
recent pesticide-use records.  We request that a minimum of ten growers take 
part in a course because of the travel time for Chemicals-Pesticides Program 
staff.  If agents/ specialists are unable to schedule a session, a request 
that direct mailing be made to growers can be arranged through our office.  
All responses are completely confidential.
     The final date for a session scheduling will be March 31, 1991.  For 
additional information, please contact the Chemicals-Pesticides Program, 5123 
Comstock Hall, Cornell University, Ithaca, NY/14853, (607) 255 1866.
     -- Chemicals-Pesticides Program, Cornell University
USEPA Well Water Survey
     The U.S. Environmental Protection Agency (EPA) has completed its five-
year National Survey of Pesticides in Drinking Water Wells (the Survey or 
NPS).  The Survey is the first and perhaps the most extensive monitoring 
survey ever undertaken to evaluate the presence of pesticides, pesticide 
degradates, and nitrate in drinking water wells in the United States.  EPA's 
Phase I Report provides national estimates of the occurrence and frequency of 
detections of nitrate and pesticides in drinking water wells.  The Phase I 
results of the Survey indicate that at least half of the nation's drinking 
water wells contain detectable amounts of nitrate, with a small percentage at 
concentrations higher than EPA's regulatory and health-based limits for 
drinking water (about 1.2% of community water system (CWS) wells and about 
2.4% of rural domestic wells).
     Based on the results of the Survey, EPA estimates that about 52.1% of the 
94,600 community water system wells in the United States contain nitrate; 
about 10.4% contain one or more pesticides; and about 7.1% may contain both.  
Of the approximately 10.5 million rural domestic wells, EPA estimates that 
about 57.0% contain nitrate, 4.2% contain one or more pesticides, and about 
3.2% contain both.   EPA estimates that less than one percent (0.6%) of rural 
domestic wells containing pesticides, or approximately 60,900 wells, contain 
at least one pesticide over a Maximum Contaminant Level (MCL) or Lifetime 
Health Advisory Level (HAL).  None of the detections of pesticides or 
pesticide degradates for CWS wells were above the MCL/HAL.  Nevertheless, 
based on its statistical analysis of the Survey results, EPA estimates that 
less than 1% (0.8%) of community water system wells contain pesticides at 
concentrations higher than the MCL or HAL for those chemicals for which an MCL 
or HAL has been established. 
     The pesticides detected most frequently in the Survey were DCPA acid 
metabolites and atrazine.  DCPA acid metabolites are degradates of DCPA, which 
is used primarily as a weed killer on lawns, turf, and golf courses, and also 
on a variety of fruits and vegetables.  In addition, ten other pesticides were 
detected at concentrations exceeding the Survey's minimum reporting limits.  
The concentrations of pesticides and pesticide degradates detected were 
usually well below levels of health concern.
     These Survey results indicate that the proportion of wells nationwide 
found to contain any particular pesticide or pesticide degradate is low.  
Considering only the proportion of wells containing pesticides over the EPA 
levels of health concern, Survey results do not demonstrate any immediate 
widespread health problem.  Survey results also show, however, that 
substantial numbers of wells, particularly rural domestic wells, could be 
affected by the presence of one or more pesticides.  In addition, substantial 
numbers of wells are affected both by the presence of nitrate and by nitrate 
over EPA levels of health concern.  These results indicate that there is need 
for continued attention to ground-water protection and additional analysis of 
the issue.  A Phase II report, to be released in 1991, will discuss EPA's 
assessment of the causes and factors associated with the occurrence of 
pesticides and nitrates in drinking water wells.
     Five pesticides -- alachlor, atrazine, dibromochloropropane (DBCP), 
ethylene dibromide (EDB), and gamma-HCH (Lindane) -- were detected in rural 
domestic wells at levels above their respective MCLs/HALs.  MCLs are 
enforceable standards established by EPA pursuant to the Safe Drinking Water 
Act as the maximum permissible level of a contaminant that is allowed in a 
public water supply.  Although they do not apply as a matter of law to rural 
domestic wells, MCLs were used as a standard of quality for source drinking 
water.  HAL s are the maximum concentration of a contaminant in water that may 
be consumed safely over an average human lifetime.
     -- EPA News Release, 11/90
News Briefs:
     Carbofuran existing stocks dates for eight voluntarily cancelled uses 
are: 
Nov. 15, 1990 -- FMC cannot sell product made before that date after that 
date, and July 15, 1991 -- the last date product with prior labeling can be 
sold or distributed by anyone, an EPA official noted this week.
     Procymidone risk data and EPA's assessment may be reviewed by the EPA's 
FIFRA Scientific Advisory Panel (SAP) at a meeting tentatively to be held
Nov. 30.
     Telone may be reviewed jointly by EPA's Science Advisory Board and SAP 
because of the two exposure routes.
     The definition developed by OPTS' Biotechnology Science Advisory 
Committee for exclusion of biotech pesticides from notification to EPA prior 
to small-scale testing was deemed "acceptable" by the FIFRA Scientific 
Advisory Panel (SAP), but only if key modifications are made, according to the 
final SAP report from its Sept. 26 meeting.
     -- Pesticide & Toxic Chemical News, Oct. 17, 1990
     EBDCs suspension negotiations are subject to monthly status reports from 
the parties beginning Nov. 15 and every 15th of the month thereafter, 
according to an order from the EPA ALJ.
     -- Pesticide & Toxic Chemical News, November 7,1990
     EPA has granted a registration for the use of acephate (Orthene 75S 
Soluble Powder) on lettuce to control aster leafhopper.
     -- W. Smith, Chemicals-Pesticides Program


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